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Helen S. Melito, Christopher R. Daubert, E. Allen Foegeding
Creep and large amplitude oscillatory shear behavior of whey protein isolate/.-carrageenan gels
Appl. Rheol. 22:6 (2012) 63691 (14 pages)
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Dynamic oscillatory and creep tests are two common rheological methods used to determine viscoelastic properties. In the
food industry, these tests are generally performed in the linear viscoelastic region, providing information on food structure
and behavior over a range of timescales. However, this small-strain testing gives an incomplete picture of structural deformation
and breakdown. Nonlinear oscillatory and creep testing, on the other hand, may yield a more complete fingerprint of
food structural behavior. In this study, whey protein isolate (WPI)/k-carrageenan gels with different structures were studied
under large amplitude oscillatory shear (LAOS) and creep tests to determine the impact of structure on nonlinear oscillatory
and creep behavior, and to examine correlations between nonlinear oscillatory and creep parameters. Evaluated structural
types comprised a homogeneous protein gel, a bicontinuous gel, in which both WPI and k-carrageenan exhibited a continuous
network, and a carrageenan continuous gel. Creep data were fit to 4-element Burgers models for further analysis, and
the predicted compliance values were found to be in agreement with experimental data (R2 ≥ 0.90). Carrageenan continuous
gels showed the greatest degree of nonlinearity under LAOS (25 % strain), while homogeneous gels displayed the least.
Nonlinear oscillatory data was found to correlate (R2 > 0.7, p < 0.05) with parameters used in the 4-element Burgers model.
Hence, nonlinear viscoelastic behavior among materials may be evaluated by both creep data and nonlinear oscillatory data.
However, nonlinear oscillatory data gives a quantitative measure of the type and extent of nonlinear behavior, while creep
data indicates only the presence of nonlinear behavior. By combining information on structural behavior derived from nonlinear
oscillatory and creep data, it is possible to determine nonlinear behavior over a wide range of timescales, yielding
insight into structural deformation and breakdown under application of stress or strain at different rates.
► Cite this publication as follows:
Melito HS, Daubert CR, Foegeding EA: Creep and large amplitude oscillatory shear behavior of whey protein isolate/.-carrageenan gels, Appl. Rheol. 22 (2012) 63691.
Y. Masubuchi,T. Morii,T. Saito, H. Ito, Ch. Nonomura
Applied Rheology discussed in the 12th Annual Meeting of the Japan Society of Polymer Processing (JSPP)
Appl. Rheol. 11:4 (2001) 230
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► Cite this publication as follows:
Masubuchi Y, Morii T, Saito T, Ito H, Nonomura C: Applied Rheology discussed in the 12th Annual Meeting of the Japan Society of Polymer Processing (JSPP), Appl. Rheol. 11 (2001) 230.
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